Below is my code with screenshot:
<!--lwcPicklistDemo.html-->
<template>
<lightning-card >
<table class="slds-table slds-table_cell-buffer slds-table_bordered slds-table_striped">
<thead>
<tr class="slds-line-height_reset">
<th scope="col"><div class="slds-truncate">Actions</div></th>
<th scope="col"><div class="slds-truncate">Id</div></th>
<th scope="col"><div class="slds-truncate">Name</div></th>
<th scope="col"><div class="slds-truncate">Type</div></th>
<th scope="col"><div class="slds-truncate">Industry</div></th>
</tr>
</thead>
<tbody>
<template for:each={sObjData} for:item="sobKey">
<tr key={sobKey.Id}>
<td><div><lightning-button variant="brand" label="Remove" title="Primary action" onclick={handleClick} class="slds-m-left_x-small"></lightning-button>
</div></td>
<td><div>{sobKey.Id}</div></td>
<td><div>{sobKey.Name}</div></td>
<td>
<div class="slds-select_container">
<select class="slds-select" onchange={onValueSelection1}>
<option value="">{sobKey.Type}</option>
<!--iterate all picklist values from wrapper list using for:each loop-->
<template for:each={TypeValue.data} for:item="picklistItem">
<option key={picklistItem.svalue} value={picklistItem.svalue}>
{picklistItem.slabel}
</option>
</template>
</select>
</div>
</td>
<td>
<div class="slds-select_container">
<select class="slds-select" onchange={onValueSelection1}>
<option value="">{sobKey.Industry}</option>
<!--iterate all picklist values from wrapper list using for:each loop-->
<template for:each={IndustryValues.data} for:item="picklistItem">
<option key={picklistItem.svalue} value={picklistItem.svalue}>
{picklistItem.slabel}
</option>
</template>
</select>
</div>
</td>
</tr>
</template>
</tbody>
</table>
</lightning-card>
</template>
/*lwcPicklistDemo.js*/
import { LightningElement,wire, api, track } from 'lwc';
import fetchsObjectData from '@salesforce/apex/lwcDemoController.fetchsObjectData';
import fetchPickListValue from '@salesforce/apex/lwcDemoController.fetchPickListValue';
export default class LwcPicklistDemo extends LightningElement {
@api objectName = 'Account';
@track sObjData= [];
@wire(fetchsObjectData, {obName :'$objectName'} )
wiredResult(result) {
if (result.data) {
this.sObjData = result.data;
}
}
@wire(fetchPickListValue, {objInfo: {'sobjectType' : 'Account'},
picklistFieldApi: 'Industry'}) IndustryValues;
@wire(fetchPickListValue, {objInfo: {'sobjectType' : 'Account'},
picklistFieldApi: 'Type'}) TypeValue;
onValueSelection1(event){
// eslint-disable-next-line no-alert
alert(event.target.value);
}
onValueSelection2(event){
// eslint-disable-next-line no-alert
alert(event.target.value);
}
handleClick(){
// eslint-disable-next-line no-alert
alert('Remove clicked');
}
}
/*lwcDemoController.apxc*/
public with sharing class lwcDemoController {
@AuraEnabled(cacheable = true)
public static List<SObject> fetchsObjectData(String obName){
return database.query('SELECT ID, Name,Type,Industry FROM '+obName+' LIMIT 5');
}
@AuraEnabled(cacheable = true)
public static List < FetchValueWrapper > fetchPickListValue(sObject objInfo, string picklistFieldApi) {
// Describe the SObject using its object type.
Schema.DescribeSObjectResult objDescribe = objInfo.getSObjectType().getDescribe();
// Get a map of fields for the SObject
map < String, Schema.SObjectField > fieldMap = objDescribe.fields.getMap();
// Get the list of picklist values for this field.
list < Schema.PicklistEntry > values = fieldMap.get(picklistFieldApi).getDescribe().getPickListValues();
// Create a list of wrapper to store picklist value/lable
list < FetchValueWrapper > objWrapper = new list < FetchValueWrapper > ();
for (Schema.PicklistEntry a: values) {
FetchValueWrapper oFetchValueWrapper = new FetchValueWrapper();
oFetchValueWrapper.slabel = a.getLabel();
oFetchValueWrapper.svalue = a.getValue();
objWrapper.add(oFetchValueWrapper);
}
return objWrapper;
}
// wrapper class
public with sharing class FetchValueWrapper {
@auraEnabled public string slabel {get;set;}
@auraEnabled public string svalue {get;set;}
}
}
<!--lwcDemoApp.app-->
<aura:application extends="force:slds">
<c:lwcPicklistDemo></c:lwcPicklistDemo>
</aura:application>

Pass the index to the button with the data attribute and get the same in the JS and use that index to get the item from the list.HTML change <!-- Rest of the above code. -->
<template for:each={sObjData} for:item="sobKey" for:index="index">
<tr key={sobKey.Id}>
<td>
<div>
<lightning-button variant="brand" label="Remove" title="Primary action" onclick={handleClick} class="slds-m-left_x-small" data-index={index}></lightning-button> <!-- Added the data-index attribute here to use in JS. -->
</div>
</td>
<!-- Rest of the below code. -->
JS Change:
I guess this is what you are looking for;⌗html5 ⌗data-api ⌗lwchandleClick(event){
const itemIndex = event.currentTarget.dataset.index;
const rowData = this.sObjData[itemIndex];
// eslint-disable-next-line no-console
console.log(rowData);
}